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Describing the Firmness, Springiness and Rubberiness of Food Gels Using Fractional Calculus. Part I: Theoretical Framework

Title

Describing the Firmness, Springiness and Rubberiness of Food Gels Using Fractional Calculus. Part I: Theoretical Framework

Publication Type
Journal Article
Year of Publication
2017
Journal
Food Hydrocolloids
Volume
62
Pagination
311-324
Publication Language
eng
Citation Key
153
COinS Data
Abstract

Constitutive models for soft solids that quantitatively relate the state of the stress in the material to the deformation history have the potential to be used in a structure-texture engineering context, but successful examples are scarce. In the present work we define equations for the firmness F, springiness S, and rubberiness R, of semi-soft food gels such as cheeses that exhibit broad power-law stress relaxation over a wide range of timescales. The equations contain only two material properties, which have their origin in the food microstructure: a fractional exponent, which quantifies the frequency and temporal response and secondly a scale factor or “quasi-property”, which sets the magnitude of the stress in the material. Together they form a constitutive element, known as the ‘springpot’ or Scott Blair element which can accurately capture the viscoelastic properties of food gels such as semi-hard cheeses. Using this model it becomes possible to provide clear and unambiguous definitions of textural parameters such as firmness, springiness and rubberiness, and to quantify their time-dependence and interrelationship. The magnitude of the firmness and springiness are inversely related through the fractional constitutive model. Our FSR-equations can be used in a texture engineering context to guide effective product reformulation of soft-solid, hydrocolloidal gels.